Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa     

Pierre Hudon  In-Ho Jung  Don R. Baker 《Physics of the Earth and Planetary Interiors》2002,130(3-4):159-174

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu_0,58Pb_12,72(Sb_7,04Bi_0,24)S₂₄Crystal structure of a Cu-poor natural meneghinite,Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄     

Yves Moëlo  Pierre Palvadeau  Nicolas Meisser  Alain Meerschaut 《Comptes Rendus Geoscience》2002,334(8):529-536

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.  相似文献   

Magnetic properties of a freshly fallen LL ordinary chondrite: the Bensour meteorite   总被引：1，自引：0，他引：1  

Jrme Gattacceca  Pierre Rochette  Michle Bourot-Denise 《Physics of the Earth and Planetary Interiors》2003,140(4):343-358

A comprehensive rock magnetic, magnetic anisotropy and paleomagnetic study has been undertaken in the brecciated LL6 Bensour ordinary chondrite, a few months only after its fall on Earth. Microscopic observations and electronic microprobe analyses indicate the presence of Ni-rich taenite, tetrataenite and rare Co-rich kamacite. Tetrataenite is the main carrier of remanence. Magnetization and anisotropy measurements were performed on mutually oriented 125 mm³ sub-samples. A very strong coherent susceptibility and remanence anisotropy is evidenced and interpreted as due to the large impact responsible for the post-metamorphic compaction of this brecciated material and disruption of the parent body. We show that the acquisition of remanent magnetization postdates metamorphism on the parent body and predates the entering of the meteorite in Earth’s atmosphere. Three components of magnetization could be isolated. A soft coherent component is closely related to the anisotropy of the meteorite and is interpreted as a shock remanent magnetization acquired during the same large impact on the parent body. Two harder components show random directions at a few mm scale. This randomness is attributed either to the formation mechanism of tetrataenite or to post-metamorphic brecciation. All components are likely acquired in very low (≈μT) to null ambient magnetic field, as demonstrated by comparison with demagnetization behavior of isothermal remanent magnetization. Two other LL6 meteorites, Kilabo and St-Mesmin, have also been studied for comparison with Bensour.  相似文献   

A comment on “The nitrogen record of crust-mantle interaction and mantle convection from Archean to Present” by B. Marty and N. Dauphas [Earth Planet. Sci. Lett. 206(2003) 397-410]     

Pierre Cartigny  Magali Ader 《Earth and Planetary Science Letters》2003,216(3):425-432

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Frequency-dependent relocation of the 1992 Nicaragua slow earthquake: an empirical Green's function approach     

Pierre F. Ihmlé 《Geophysical Journal International》1996,127(1):75-85

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Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle   总被引：4，自引：0，他引：4  

Pierre Schiano  Jean-Louis Birck  Claude J. Allgre 《Earth and Planetary Science Letters》1997,150(3-4):363-379

Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (¹⁸⁷Os/¹⁸⁶Os and ¹⁸⁷Os/¹⁸⁸Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.  相似文献   

Crystal morphologies in pillow basalts: implications for mid-ocean ridge processes     

Franois Faure  Pierre Schiano 《Earth and Planetary Science Letters》2004,220(3-4):331-344

We present the results of a detailed petrological study of a sparsely phyric basalt (MAPCO CH98-DR11) dredged along the Mid-Atlantic Ridge (30°41′N). The sample contains microphenocrysts of olivine that display four different rapid-growth morphologies. Comparison of these morphologies with those obtained in dynamic crystallization experiments allows us to constrain the thermal history of the sample. The dendritic morphology (swallowtail, chain and lattice olivine) is directly related to the final quenching during magma–seawater interaction. In contrast, the three other morphologies, namely the complex polyhedral crystal, the closed hopper and the complex swallowtail morphology result from several cycles of cooling–heating (corresponding to a maximum degree of undercooling of 20–25°C) during crystal growth. These thermal variations occurred before eruption and are interpreted to be the result of turbulent convection in a small magmatic body beneath the ridge. The results suggest that the Mid-Atlantic Ridge is underlain by a mush zone that releases batches of liquid during tectonic segregation. Aphyric basalts are emitted during eruptions controlled by the tectonic activity, whereas phyric basalts correspond to small fractions of magma from the mush zone mobilized by reinjections of primitive magmas.  相似文献   

Fitting the Linear Model of Coregionalization by Generalized Least Squares   总被引：2，自引：0，他引：2  

Bernard Pelletier  Pierre Dutilleul  Guillaume Larocque  James W. Fyles 《Mathematical Geology》2004,36(3):323-343

In geostatistical studies, the fitting of the linear model of coregionalization (LMC) to direct and cross experimental semivariograms is usually performed with a weighted least-squares (WLS) procedure based on the number of pairs of observations at each lag. So far, no study has investigated the efficiency of other least-squares procedures, such as ordinary least squares (OLS), generalized least squares (GLS), and WLS with other weighing functions, in the context of the LMC. In this article, we compare the statistical properties of the sill estimators obtained with eight least-squares procedures for fitting the LMC: OLS, four WLS, and three GLS. The WLS procedures are based on approximations of the variance of semivariogram estimates at each distance lag. The GLS procedures use a variance–covariance matrix of semivariogram estimates that is (i) estimated using the fourth-order moments with sill estimates (GLS₁), (ii) calculated using the fourth-order moments with the theoretical sills (GLS₂), and (iii) based on an approximation using the correlation between semivariogram estimates in the case of spatial independence of the observations (GLS₃). The current algorithm for fitting the LMC by WLS while ensuring the positive semidefiniteness of sill matrix estimates is modified to include any least-squares procedure. A Monte Carlo study is performed for 16 scenarios corresponding to different combinations of the number of variables, number of spatial structures, values of ranges, and scale dependence of the correlations among variables. Simulation results show that the mean square error is accounted for mostly by the variance of the sill estimators instead of their squared bias. Overall, the estimated GLS₁ and theoretical GLS₂ are the most efficient, followed by the WLS procedure that is based on the number of pairs of observations and the average distance at each lag. On that basis, GLS₁ can be recommended for future studies using the LMC.  相似文献   

Petrology and geochemistry of a diamondiferous lherzolite from the Premier diamond mine, South Africa     

K.S. Viljoen  Ren Dobbe  Braam Smit  Emilie Thomassot  Pierre Cartigny 《Lithos》2004,77(1-4):539-552

This paper reports on the petrology and geochemistry of a diamondiferous peridotite xenolith from the Premier diamond mine in South Africa.

The xenolith is altered with pervasive serpentinisation of olivine and orthopyroxene. Garnets are in an advanced state of kelyphitisation but partly fresh. Electron microprobe analyses of the garnets are consistent with a lherzolitic paragenesis (8.5 wt.% Cr₂O₃ and 6.6 wt.% CaO). The garnets show limited variation in trace element composition, with generally low concentrations of most trace elements, e.g. Y (<11 ppm), Zr (<18 ppm) and Sr (<0.5 ppm). Garnet rare earth element concentrations, when normalised against the C1 chondrite of McDonough and Sun (Chem. Geol. 120 (1995) 223), are characterised by a rare earth element pattern similar to garnet from fertile lherzolite.

All diamonds recovered are colourless. Most crystals are sharp-edged octahedra, some with minor development of the dodecahedral form. A number of crystals are twinned octahedral macles, while aggregates of two or more octahedra are also common. Mineral inclusions are rare. Where present they are predominantly small black rosettes believed to consist of sulfide. In one instance a polymineralic (presumably lherzolitic) assemblage of reddish garnet, green clinopyroxene and a colourless mineral is recognised.

Infrared analysis of the xenolith diamonds show nitrogen contents generally lower than 500 ppm and variable nitrogen aggregation state, from 20% to 80% of the ‘B’ form. When plotted on a nitrogen aggregation diagram a well defined trend of increasing nitrogen aggregation state with increasing nitrogen content is observed. Carbon isotopic compositions range from −3.6 ‰ to −1.3 ‰. These are broadly correlated with diamond nitrogen content as determined by infrared spectroscopy, with the most negative C-isotopic compositions correlating with the lowest nitrogen contents.

Xenolith mantle equilibration temperatures, calculated from nitrogen aggregation systematics as well as the Ni in garnet thermometer are on the order of 1100 to 1200 °C.

It is concluded that the xenolith is a fertile lherzolite, and that the lherzolitic character may have resulted from the total metasomatic overprinting of pre-existing harzburgite. Metasomatism occurred prior to, or accompanied, diamond growth.  相似文献   

Modélisation morphodynamique cross-shore d'un estran vaseux     

Benoı̂t Waeles  Pierre Le Hir  Ricardo Silva Jacinto 《Comptes Rendus Geoscience》2004,336(11):1025-1033

Numerical experiments were performed to simulate the profile evolution of an intertidal mudflat with a 1D cross-shore morphodynamical model. First, the hydrodynamical forcing is a cross-shore tidal current due to semi-diurnal variations of the free surface elevation at the open boundary. Further, considering the conservation of the action density of surface gravity waves, a wave height (and resulting bottom shear stress) calculation is added to the morphodynamical model. Results of the numerical experiments show that the shape of the profile reaches equilibrium. The mudflat progrades continually when the forcing is tide only, whereas it can be steady under the simultaneous action of tide and waves. To cite this article: B. Waeles et al., C. R. Geoscience 336 (2004).  相似文献